Academic Thesis

Basic information

Name Horikoshi Ryo
Belonging department
Occupation name
researchmap researcher code 7000023044
researchmap agency Okayama University of Science

Title

Preparation and Structures of Copper(II) and Zinc(II) Complexes with 5-Ferrocenylpyrimidine: Structural Variation Derived from Flexible Coordination Ability of the Ligand and Metal Ions

Bibliography Type

 

Author

Horikoshi, R
Okazawa, K
Mochida, T

Summary

5-Ferrocenylpyrimidine (FcPM) reacts with dinuclear copper(II) carboxylates ([Cu-2(RCOO)(4)]; R = C6H5, C5H11, CH3) to produce one-dimensional coordination polymers [Cu-2(C6H5COO)(4)(FcPM)](n) (1), [Cu-2(C5H11COO)(4)(FcPM)](n) center dot nCH(3)CN (2), and a discrete tetranuclear complex [Cu-2(CH3COO)(4)(FcPM)(2)] (3). Compounds I and 2 show similar zigzag chain structures, comprising alternate linking of FcPM and dinuclear copper(II) units, whereas the structure of 3 corresponds to the local structural motifs of 1 and 2. Reaction of FcPM with zinc salts (ZnX2; X = NO3, SCN) affords zinc-centered ferrocenyl cluster complexes, [Zn(NO3)(2)(FcPM)(3)] (4) and [Zn(SCN)(2)(FcPM)(2)] center dot 0.5H(2)O (5), with varying M:L ratios. FcPM acts as a bidentate ligand in 1 and 2, and as a monodentate ligand in the others. (c) 2005 Elsevier B.V. All rights reserved.

Magazine(name)

Journal of Organometallic Chemistry

Publisher

ELSEVIER SCIENCE SA

Volume

690

Number Of Pages

7

StartingPage

1793

EndingPage

1799

Date of Issue

2005-03

Referee

Exist

Invited

Not exist

Language

English

Thesis Type

Research papers (academic journals)

ISSN

 

DOI

10.1016/j.jorganchem.2005.02.003

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