Academic Thesis

Basic information

Name Horikoshi Ryo
Belonging department
Occupation name
researchmap researcher code 7000023044
researchmap agency Okayama University of Science

Title

Supramolecular isomerism in self-assembled complexes from 4,4 '-dipyridyl disulfide and M(hfac)(2): Coordination polymers (M = Mn) and metallamacrocycles (M = Co, Ni)

Bibliography Type

 

Author

R Horikoshi
T Mochida
M Kurihara
M Mikuriya

Summary

Correlations between the reaction conditions and resultant structures have been investigated in detail for supramolecules of M(hfac)(2) (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonate) with 4pds (4pds = 4,4'-dipyridyl disulfide). It was revealed that coordination polymers are selectively obtained for M = Mn and Cu and metallamacrocycles are obtained for M = Co and Ni. The Mn complex [Mn(hfac)(2)4pds](n) was found to exhibit supramolecular isomerism depending on the reaction solvent, forming compounds with zigzag achiral chains (1) from methanol and helical chiral chains (2) from tetrachloromethane. The metallamacrocycles [M(hfac)(2)(4pds)](2).4CHCl(3) (M = Co 3; M = Ni 4) and [M(hfaC)(2)(4pds)](2).H2O (M = Co 5; M = Ni 6) are composed of two M(hfaC)2 units and two ligands with the same chirality. The macrocycles are chiral and change their shape slightly depending on the guests accommodated above and below the cavities.

Magazine(name)

CRYSTAL GROWTH & DESIGN

Publisher

AMER CHEMICAL SOC

Volume

5

Number Of Pages

1

StartingPage

243

EndingPage

249

Date of Issue

2005-01

Referee

Exist

Invited

Not exist

Language

English

Thesis Type

Research papers (academic journals)

ISSN

 

DOI

10.1021/cg0499109

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PMID

 

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arXiv ID

 

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DBLP ID