Uptake of carbon monoxide by a sulfur-bridged molybdenum-nickel cluster.  Synthesis and structure of [Mo3NiS4(CO)(H2O)9]4+

Shibahara, Takashi; Mochida, Shinichi; Sakane, Genta

crystal structure molybdenum nickel sulfido carbonyl; structure molybdenum nickel aqua sulfido carbonyl; molybdenum nickel aqua sulfido carbonyl cluster; cubane molybdenum nickel aqua sulfido carbonyl
Cubane-type cluster [Mo3NiS4(H2O)10]4+ uptakes CO in dil. HCl to give [Mo3NiS4(CO)(H2O)9]4+.  The x-ray structure anal. verified that the Ni atom has a tetrahedral configuration surrounded by 1 CO and 3 S's neglecting 3 Ni-Mo bonds (triclinic, space group P.hivin.1, R = 0.0811).

Chemistry Letters

Chemical Society of Japan

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