Solid-state materials and clusters. Sulfur-bridged incomplete cubane-type molybdenum and tungsten aqua ions

Sakane, Genta; Shibahara, Takashi; Enemark, John H.; McMaster, Jonathan; Valek, Michael

molybdenum tungsten sulfide aqua cluster ion prepn
The procedures for the synthesis of the aqua clusters [Mo3S4(H2O)9]4+ and [W3S4(H2O)9]4+, which were obtained by the redn. of (NH4)2MS4 (M = Mo, W) with NaBH4 in dil. HCl, are described.

Inorganic Syntheses

John Wiley & Sons, Inc.

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