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| 基本情報 |
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| 氏名 |
堀越 亮 |
| 氏名（カナ） |
ﾎﾘｺｼ ﾘｮｳ |
| 氏名（英語） |
Horikoshi Ryo |
| 所属 |
機構 教育推進機構 基盤教育ｾﾝﾀｰ |
| 職名 |
教授 |
| researchmap研究者コード |
7000023044 |
| researchmap機関 |
岡山理科大学 |
Side-Chain Coordination Polymers Containing Redox-Active Pendants: Complexation of Ferrocene-Based Bidentate Ligands with M(hfac)2 (hfac=1,1,1,5,5,5-Hexafluoroacetylacetonate, M = Mn, Ni, Cu, Zn) and CuX (X = I, Br)
Horikoshi, R
Ueda, M
Mochida, T
Coordination polymers with redox active pendants, {5-ferrocenylpyrimidine.M(hfac)(2)}(n) [M=Mn (1a), Ni (1b), Cu (1c), Zn (1d)] and {5-ferrocenylpyrimidine.CuX}(n) [X=I (2a), Br (2b)], have been prepared and characterized. In complex 1c, the Cu(II) ions are linked by the bridging ligands to form one-dimensional chains. This complex was shown to exhibit an antiferromagnetic intra-chain interaction, which was analyzed by the Bonner-Fisher model (2J/k(B) = -6.3 K). Complex 2a shows a two-dimensional sheet-like structure, in which one-dimensional chains, consisting of the Cu(I) ions and the ligands, are further bridged by iodide anions. These compounds show quasi-reversible redox processes of the ferrocenyl groups in the solid state.
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