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| 基本情報 |
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| 氏名 |
若松 寛 |
| 氏名（カナ） |
ﾜｶﾏﾂ ｶﾝ |
| 氏名（英語） |
Wakamatsu Kan |
| 所属 |
理学部 化学科 |
| 職名 |
准教授 |
| researchmap研究者コード |
1000194580 |
| researchmap機関 |
岡山理科大学 |
Desulfonylative Radical Truce-Smiles Rearrangement Utilizing the Benzimidazoline and Benzimidazolium Redox Couple
Ryo Miyajima, Manon Okamura, Kazuki Oomori, Hajime Iwamoto, Kan Wakamatsu, Eietsu Hasegawa
Here authors developed protocols for promoting redox reactions utilizing the 2-substituted 1,3-dimethylbenzimidazoline (BIH-R) and benzimidazolium (BI+-R) couples which were applied to the desulfonylativeradical Truce-Smiles rearrangement. Expected rearrangement products formed in modest to good yields in these processes, in which added or in situ generated BIH-R serve as electron- and hydrogen-atom-donating reagents or photocatalysts. DFT calculations were carried out to gain the inform ation about the radical intermediates involved in the rearrangement reaction.
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