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| 基本情報 |
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| 氏名 |
坂根 弦太 |
| 氏名（カナ） |
ｻｶﾈ ｹﾞﾝﾀ |
| 氏名（英語） |
Sakane Genta |
| 所属 |
機構 教育推進機構 基盤教育ｾﾝﾀｰ 科学技術教育部門 |
| 職名 |
教授 |
| researchmap研究者コード |
1000194578 |
| researchmap機関 |
岡山理科大学 |
希少糖単糖およびデオキシ糖における水素結合ネットワークとエネルギー準位の比較
希少糖
Rare sugars are defined by 'The International Society of Rare Sugars' as "monosaccharides and their derivatives that rarely exist in nature". In contract, sugar in nature large amounts is called natural sugar. Although isomerization from natural monosaccharide to rare sugar is very difficult for the organic chemists, a novel enzyme called DTE (D-tagatose-3-epimerase) has been discovered. The DTE isomerizes from D-fructose to D-psicose. In this work, we synthesized the single crystal of the deoxy rare sugar, and the crystal structural data have been obtained. We also investigated the comparison of hydrogen-bonding network and energy level structure for rare sugar monosaccharide and deoxy rare sugar by means of molecular orbital calculation, DV-Xα method. In addition, disorder structure can be found in sorbose. We have also investigated the reason of the disorder structure through the hydrogen-bonding network.
Bulletin of the Society for Discrete Variational Xα
The Society for Discrete Variational Xα
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