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| 基本情報 |
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| 氏名 |
坂根 弦太 |
| 氏名（カナ） |
ｻｶﾈ ｹﾞﾝﾀ |
| 氏名（英語） |
Sakane Genta |
| 所属 |
教育推進機構 基盤教育ｾﾝﾀｰ 科学技術教育部門 |
| 職名 |
教授 |
| researchmap研究者コード |
1000194578 |
| researchmap機関 |
岡山理科大学 |
Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands
Ohta, Hiromi; Harada, Kenji; Irie, Koji; Kashino, Setsuo; Kambe, Takashi; Sakane, Genta; Shibahara, Takashi; Takamizawa, Satoshi; Mori, Wasuke; Nonoyama, Matsuo; Hirotsu, Masakazu; Kojima, Masaaki
crystal structure nickel methoxysalicylideneaminomethylethane dinuclear trinuclear; spin exchange nickel methoxysalicylideneaminomethylethane dinuclear trinuclear; nickel salicylideneaminomethylethane methoxysalicylideneaminomethylethane dinuclear trinuclear prepn; hydrogen bond nickel methoxysalicylideneaminomethylethane dinuclear
The reaction of Ni2+ with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and its 5-methoxy analog afforded the O-H...O bridged dinuclear [Ni2(HL)2] complexes. When Ni2+ was allowed to react with H3L in the presence of NEt3 (3:2:6), the linear trinuclear [Ni3(L)2] complex formed, where the central Ni(II) ion is bridged by six phenolate O atoms to the terminal Ni(II) ions. The prepn. of the NiII-MII-NiII (M = Mn, Co) heterotrinuclear complexes is also reported.
Chemical Society of Japan
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