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| 基本情報 |
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| 氏名 |
坂根 弦太 |
| 氏名（カナ） |
ｻｶﾈ ｹﾞﾝﾀ |
| 氏名（英語） |
Sakane Genta |
| 所属 |
機構 教育推進機構 基盤教育ｾﾝﾀｰ |
| 職名 |
教授 |
| researchmap研究者コード |
1000194578 |
| researchmap機関 |
岡山理科大学 |
catena-Poly[[diaquazinc(II)]-μ-L-cysteinato(2-)-κ4S:S,N,O-[di-μ-sulfido-bis[oxidomolybdate(V)](Mo-Mo)]-μ-L-cysteinato(2-)-κ4S,N,O:S]
Shibahara, Takashi; Ogasahara, Shinobu; Sakane, Genta
The title compound, [Mo2Zn(C3H5NO2S)2O2S2(H2O)2], forms a one-dimensional chain. The cysteine S atom of the dinuclear molybdenum complex anion coordinates to the zinc ion, which has a tetrahedral environment by the additional coordination of two water molecules. The one-dimensional chains are connected to each other by hydrogen bonds. The Zn-S(cysteine) distances [2.3599 (6) and 2.3072 (6) Å] are close to the value in ZnS (2.35 Å). The distances and angles within the complex are very close to those reported for the sodium and potassium di-μ-sulfide species.
http://dx.doi.org/10.1107/S1600536808007757
Acta Crystallographica, Section E: Structure Reports Online
International Union of Crystallography
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