論文

基本情報

氏名 満身 稔
氏名(カナ) ミツミ ミノル
氏名(英語) Mitsumi Minoru
所属 理学部 化学科
職名 教授
researchmap研究者コード 5000022891
researchmap機関 岡山理科大学

題名

Redox-triggered reversible modulation of intense near-infrared and visible absorption using a paddlewheel-type diruthenium(III) complex

単著・共著の別

共著

著者

Yusuke Kataoka, Nanako Imasaki, Natsumi Yano, Minoru Mitsumi, and  Makoto Handa

概要

A new paddlewheel-type diruthenium complex with 2-amino-3-(trifluoromethyl)pyridine (amtfmp) [Ru2(amtfmp)4Cl2] ([1]), which shows intense and characteristic near-infrared (NIR) and visible absorption, has been developed and structurally characterized by single crystal X-ray diffraction (SCXRD) analyses. This complex exhibits reversible and dramatic NIR and visible electrochromic behavior from deep-blue ([1]) to pink ([1]) due to the ON–OFF switching of its characteristic ligand-to-metal charge transfer (LMCT) and d–d absorption bands in response to an external voltage or chemical reagent such as decamethylcobaltocene (CoCp*2). The one-electron reduced species of [1], i.e., [CoCp*2][1], was successfully isolated and fully characterized via SCXRD, the temperature dependence of the magnetic susceptibility, and mass spectroscopy, proving that this electrochromic behavior occurs without significant structural reorganization of [1].

発表雑誌等の名称

Dalton Trans., 2021, 50, 9547–9553 (https://doi.org/10.1039/D1DT01681D)

出版者

50

開始ページ

9547

終了ページ

9553

発行又は発表の年月

2021/06

査読の有無

有り

招待の有無

無し

記述言語

掲載種別

ISSN

ID:DOI

doi.org/10.1039/D1DT01681D

ID:NAID(CiNiiのID)

ID:PMID

URL

JGlobalID

arXiv ID

ORCIDのPut Code

DBLP ID