Evaluation of thermodynamic model of Pd(II) complex formation with isosaccharinic acid

Shingo Kimuro, Yayoi Tanaichi, Hajime Iwata, Takamitsu Ishidera, Akira Kitamura, Yukio Tachi, Takeru Tanaka, Kana Hirono, Manami Hieda, Shunsuke Miyabe, Daisuke Kawamoto

Palladium-107 is one of the selected radionuclides in the safety assessment of geological disposal of radioactive waste. Although isosaccharinic acid (ISA) forms strong complexes with many elements and enhances element solubility, the thermodynamic evaluation of the complex of Pd with ISA has not been conducted. In this study, the solubility of Pd(OH)2 at pH 8.5–12.5 in the presence of ISA was investigated under inert gas (N2) atmosphere. Furthermore, the coordination state of aqueous Pd and ISA was investigated by X-ray absorption and Fourier transform infrared spectroscopy, respectively. According to experimental results, the number of OH ligands in the mixed complex depends on pH. The thermodynamic model and conditional equilibrium constants of the Pd-ISA complex were estimated by slope analyses of solubility experiments at different pH levels and ionic strengths based on the specific ion interaction theory. Hence, the impact of complexation with ISA on Pd(II) solubility under disposal conditions could be quantified using the proposed thermodynamic models in this study.

Jornal of Solution Chemistry

https://doi.org/10.1007/s10953-023-01352-6